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Internally Gnus uses a format for storing article headers that corresponds to the NOV format in a mysterious fashion. One could almost suspect that the author looked at the NOV specification and just shamelessly stole the entire thing, and one would be right.
Header is a severely overloaded term.  "Header" is used in
RFC 1036 to talk about lines in the head of an article (e.g.,
From).  It is used by many people as a synonym for
"head"---"the header and the body".  (That should be avoided, in my
opinion.)  And Gnus uses a format internally that it calls "header",
which is what I'm talking about here.  This is a 9-element vector,
basically, with each header (ouch) having one slot.
These slots are, in order: number, subject, from,
date, id, references, chars, lines,
xref, and extra.  There are macros for accessing and
setting these slots--they all have predictable names beginning with
mail-header- and mail-header-set-, respectively.
All these slots contain strings, except the extra slot, which
contains an alist of header/value pairs (see section 3.1.2 To From Newsgroups).